Product ID:NASHUA XD-41, XD-45, XD-48, XD-50
MSDS Date:07/10/1996
FSC:6850
NIIN:01-253-1260
Status Code:A
MSDS Number: CKLNY

Emergency Phone: 303-623-5716

Info Phone: 603-880-2323

Cage: 82784

Telephone: 603-880-2323

Cage: 82784

CARRIER (IRON GRANULAES, CAS#7439-89-6, >95%; ACRYLATE

TONER (STYRENE ACRYLATE POLYMER, CAS# 25213-39-2, 80-90%;

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE (PERTAINS TO FINISHED PRODUCT):
EYE: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. REPEATED
CONTACT MAY CAUSE IRRITATION; MAY CAUSE ALLERGIC SKIN REACTION.
INHALATION: INHALATION OF DUST COU LD CAUSE UPPER RESPIRATORY
IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE MUCOUS MEMBRANES
OR DIGESTIVE TRACT.
Explanation of Carcinogenicity:IARC IS BASED ON AMINAL LABORATORY
STUDIES SPECIFICALLY RATS.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF RUNNING WATER FOR AT
LEAST 15 MINS. OBTAIN MEDICAL ATTNETION. SKIN: FLUSH AFFECTED AREAS
PROMPTLY WITH WATER FOR 15 MINS. REMOVE CONTAMINATED CLOTHING. IN
CASE OF CONTINUED IRRITATION, CONSULT PHYSICIAN. INHALATION: FOR
OVER-EXPOSURE, REMOVE TO FRESH AIR. INGESTION: OBTAIN IMMEDIATE
MEDICAL ATTENTION.

Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:CONTAINERS SHOULD BE KEPT COOL WITH WATER
SPRAY. TO AVOID INHALATION OF TOXIC FUMES WEAR MSHA/NIOSH APPROVED
SELF CONTAINED BREATHING APPARATUS
Unusual Fire/Explosion Hazard:TONER, LIKE MOST INORGANIC MATERIALS IN
POWDER FORM, WHEN DISPERSED IN AIR, CAN FORM EXPLOSIVE MISTURES
THAT CAN PRODUCE TOXIC FUMES SUCH AS CARBON MONOXIDE AND CO.

Spill Release Procedures:CUT OFF ALL SOURCES OF IGNITION. SWEEP UP OR
VACUUM SPILLED TONER & CAREFULLY TRANSFER INTO A SEALABLE WASTE
CONTAINER, SWEEP SLOWLY TO MINIMIZE GENERATION OF DUST DURING
CLEAN-UP. IF A VACUUM IS USED , THE MOTOR MUST BE RATED DUST TIGHT.
A CONDUCTIVE HOSE BONDED TO THE MACHINE SHOULD BE USED TO REDUCE
STATIC BUILD-UP. RESIDUE CAN BE REMOVED WITH SOAP & COLD WATER.

Handling and Storage Precautions:AVOID EYE & SKIN CONTACT, & STORE IN
WELL-VENTILATED AREA. KEEP CONTAINER TIGHTLY CLOSED & KEEP AWAY
FROM HEAT, SPARKS, & OPEN FLAME. DO NOT STORE WITH INCOMPATIBLE
MATERIALS. DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREA
WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL.
Other Precautions:IN CANADA ALL OUTSIDE CONTAINERS MUST BE LABELED AS A
WHMIS CLASS D2A CONTROLLED SUBSTANCE.

Respiratory Protection:USE NIOSH CERTIFIED DUSK MASK IF DUST IS
PRESENT. BE SURE TO MAINTAIN NORMAL ROOM VENTILATIUON (10 CHANGES
OF AIR PER HOUR).
Ventilation:ROOM VENTILATION IS SUFFICIENT. AVOID USE OF PRODUCT IN
UNVENTILATED AREAS. ALWAYS CONTROLL AIRBORNE LEVELS BELOW THE
EXPOSURE GUIDELINES.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:EYE GLASSES WITH SIDE SHIELDS OR GOGGLES.
Other Protective Equipment:CHEMICAL RESISTANT GLOVES AND APRONS.
DISPOSABLE COVERALLS ARE OPTIONAL AND DISCARD AFTER USE.
Work Hygienic Practices:GARMENTS MAY BE WASHED OR DRY CLEANED, AFTER
REMOVAL OF LOOSE TONER.
Supplemental Safety and Health
FOR OFFICE EQUIPMENT: NO PERSONAL PROTECTION EQUIPMENT IS SUGGESTED.

HCC:N1
NRC/State Lic Num:`
Spec Gravity:APPROX 7.0 (H20=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK GRANULAR POWDER, SLIGHT ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZERS.
Stability Condition to Avoid:FLAME OR EXCESSIVE HEAT.
Hazardous Decomposition Products:CO, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:ACCORDING TO FEDERAL REGULATION 40 CFR 261, THIS
MATERIAL IS NOT A HAZARDOUS WASTE WHEN DISCARDED. HOWEVER, STATE &
LOCAL REQUIREMENTS MAY BE MORE RESTRICTIVE. THEREFORE, CONSULTATION
WITH THE PROPER STATE & LOCAL AUTHORITIES IS ADVISED. INCINERATION
IS RECOMMENDED & ONLY IN A CLOSED CONTAINER.

Toxicological Information:CHRONIC HEALTH EFFECTS: CARBON BLACK-THE
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), ON APRIL 12,
1996 PUBLISHED "MOMOGRAPH VOLUME 65", WHICH RECLASSIFIES CARBON
BLACK FROM CATEGORY 2B (KNOWN ANIMAL CARCINOGEN, POSSIBLE HUMAN
CARCINOGEN). THIS CHANGE WAS BASED ON THE RESULTS OF RAT INHALATION
OF CARBON BLACK, DESPITE THE LACK OF ANY PARALLEL EVIDENCE IN
HUMANS OR OTHER ANIMAL SPECIES. BASE D ON THE LABORATORY EVIDENCE
AVAILABLE, THE CARBON BLACK INDUSTRY BELIEVES THAT CARBON BLACK IS
NOT CARCINOGENIC TO HUMANS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:GENERAL: THIS CHEMICAL FORMULATION HAS NOT BEEN TESTED FOR
ENVIRONMENTAL EFFECTS. ALTHOUGH, IN A SPILL SITUATION THIS
FORMULATION MAY BE AESTHETICALLY UNPLESANT, IT IS WATER INSOLUBLE,
AND IS NOT EXPE CTED TO SHOW ANY ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:DOT, IMO, IATA/ICAO, TRANSPORT CANADA:
NON-REGULATED. IN UNITED STATES: ALL OUTSIDE CONTAINERS MUST BE
MARKED ACCORDING TO OSHA RIGHT-TO-KNOW REGULATIONS 29 CFR,
1910.1200: AS FOLLOWS: CARBON BLACK - DUST INHALATION. IN
CANADA:MUST BE LABELED UNDER WHMIS AS A D2A CONTROLLED SUBSTANCE.

SARA Title III Information:SARA HAZARD CATEGORIES: NONE.
Federal Regulatory Information:OSHA: HAZARD COMMUNICATION RULE, 29 CFR,
1910.1200: CARBON BLACK. TSCA: ALL INGREDIENTS IN THIS FINISHED
PRODUCT ARE LISTED ON THE EPA TSCA INVENTORY. CERCLA HAZARDOUS
SUBSTANCE: NOT LISTED.
State Regulatory Information:FLORIDA. RHODE ISLAND.